Isotope Effects in Proton-transfer Reactions. VII. Deuterium Solvent Isotope Effect and Primary Kinetic Isotope Effect on the Racemization of 2-Phenylpropionitrile in Methanol/Methanol-O-d.
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چکیده
منابع مشابه
Kinetic isotope effect on the proton-transfer in indigo carmine
We have found that photo-excited indigo carmine causes stepwise proton transfer to generate monoalcohol intermediate, which immediately returns to the parent molecule [I. Iwakura, A. Yabushita, T. Kobayashi, Chem. Lett. 38 (2009) 1020]. The kinetic isotope effect in the proton transfer of this system has been studied by direct observation of the real-time molecular vibrational amplitude during ...
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ژورنال
عنوان ژورنال: Acta Chemica Scandinavica
سال: 1976
ISSN: 0904-213X
DOI: 10.3891/acta.chem.scand.30a-0421